A Resilient In-Situ Raman-Based Framework for Identifying Thermally Aged Microplastics: Validation in Waste-to-Energy Incineration
The foundational paper behind OpenMNP. Using in-situ Raman spectroscopy, we captured real-time spectral evolution of 8 representative plastics during thermal transformation (25°C to 800°C) and built the first comprehensive spectral library for thermally aged microplastics. The open-access identification framework introduced the novel concept of “MP derivative” to refine polymer classification, elevating the median spectral matching degree from 47% to 91% and reducing unassigned spectra by 76%. Applied to flue gas samples from an industrial grate furnace WtE incinerator, over 89% of emitted MPs exhibited spectral signatures consistent with thermally transformed derivatives.
Su T, Gu X, Deng S*, Wang H, Zhu W, Li Z, Li S, Wu F*. Environ. Sci. Technol. 2026.
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